OpenTF vs. Chef, Puppet, etc.
Configuration management tools install and manage software on a machine that already exists. OpenTF is not a configuration management tool, and it allows existing tooling to focus on their strengths: bootstrapping and initializing resources.
OpenTF focuses on the higher-level abstraction of the datacenter and associated services, while allowing you to use configuration management tools on individual systems. It also aims to bring the same benefits of codification of your system configuration to infrastructure management.
If you are using traditional configuration management within your compute instances, you can use OpenTF to configure bootstrapping software like cloud-init to activate your configuration management software on first system boot.